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10- Zoro saves Brook (Episode 357) / Sanji saves Usopp (Episode 297)
9- Luffy saves King Neptune (Episode 553)
8- Kizaru arrives at Sabaody (Episode 401)
7- Katakuri’s first appearance (Episode 825)
6- Aokiji saves Smoker (Episode 624)
5- Rayleigh saves Zoro (Episode 404)
4- Monkey D. Dragon saves Luffy (Episode 53)
3- Kaido’s first appearance (Episode 739)
https://www.youtube.com/watch?v=NqKl54SYegE
2- Luffy arrives at Marineford (Episode 465)
1- Shanks arrives at Marineford (Episode 488)
